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Discovery of Ice XXI: A New Phase of Ice at Room Temperature

10/16/2025, 3:02:06 AM

Overview of the Discovery

Scientists from the Korea Research Institute of Standards and Science (KRISS) have identified a new phase of ice, termed ice XXI, which forms at room temperature under extreme pressure conditions. This discovery was made during experiments utilizing the European X-Ray Free-Electron Laser Facility (XFEL) and PETRA III, where water was subjected to pressures of up to 2 gigapascals—approximately 20,000 times the normal atmospheric pressure.

Experimental Methodology

The researchers employed diamond anvil cells (DACs) to rapidly compress water within a span of 10 milliseconds, followed by a gradual release of pressure over one second. Throughout this process, the XFEL captured images of the molecular structure at an unprecedented rate of one million images per second. This allowed scientists to observe the crystallization pathways of water as it transitioned into ice XXI, which has a tetragonal crystal structure composed of large repetitive units containing 152 water molecules.

Characteristics of Ice XXI

Ice XXI is classified as a metastable phase, meaning it can exist temporarily even when other forms of ice would be more stable under similar conditions. The formation of ice XXI occurs within the pressure range of ice VI, a phase believed to exist in the interiors of icy moons such as Titan and Ganymede. The unique properties of ice XXI suggest that there may be additional, yet undiscovered, high-temperature metastable ice phases.

Implications for Astrophysics

The discovery of ice XXI has significant implications for understanding the composition and behavior of water in extraterrestrial environments. The findings indicate that various high-pressure ice phases could exist on icy moons and planets, potentially influencing our understanding of their geophysical and chemical processes. Geun Woo Lee, a senior author of the study, emphasized the importance of these findings in exploring the complexities of water's solid state and its various crystalline forms.

Official Statements & Responses

The research team expressed optimism about the potential for discovering more ice phases. Geun Woo Lee stated, "Our findings suggest that a greater number of high-temperature metastable ice phases and their associated transition pathways may exist." Rachel Husband, another co-author, noted that these insights could enhance our understanding of icy moons in the Solar System.

Criticism & Opposition

While the study presents groundbreaking findings, some experts caution against overextending the implications of ice XXI. Critics argue that further research is necessary to fully understand the stability and formation conditions of this new phase, as well as its relevance to extraterrestrial ice formations.

Verbatim Quotes

  • “With the unique X-ray pulses of the European XFEL, we have uncovered multiple crystallization pathways in water which was rapidly compressed and decompressed over 1,000 times using a dynamic diamond anvil cell,” — Geun Woo Lee, KRISS
  • “Our findings suggest that a greater number of high-temperature metastable ice phases and their associated transition pathways may exist,” — Rachel Husband, Deutsches Elektronen-Synchrotron

Conclusion

The discovery of ice XXI marks a significant advancement in the study of water's solid forms, revealing the complexities of ice formation under extreme conditions. As researchers continue to explore the implications of this new phase, it may pave the way for deeper insights into the nature of icy bodies in our Solar System.